嵟怴偺尋媶徯夘
嬥懏暘巕儚僀儎乕偵挧愴両
[ 儕儕乕僗丗 2020.02 ]
撧椙彈巕戝妛 棟妛晹 壔妛椞堟
乮桳婡嬥懏丒嶖懱壔妛尋媶僌儖乕僾乯
拞慜壚撨巕丒拞搰棽峴丒扞悾抦柧
丂壔妛偱偼乽徣帒尮傗徣僄僱儖僊乕乿傪栚巜偟偨暔幙偯偔傝偵乽僫僲僒僀僄儞僗乿偲偄偆峫偊曽偑偁傝傑偡丅偙傟偼丄條乆側摥偒傪偡傞暔幙偺僒僀僘傪壜擻側尷傝彫偝偔偡傞偙偲偱丄偦傟偵昁梫側僄僱儖僊乕傗尨椏側偳傪旘桇揑偵彮側偔偟傛偆偲偄偆傕偺偱偡丅2016擭偺僲乕儀儖壔妛徿偼,乽for the design and synthesis of molecular machines乮暘巕婡夿偺愝寁偲崌惉乯乿偲偄偆僥乕儅偱Jean-Pierre Sauvage, Sir James Fraser Stoddart, Bernard L. Feringa偺3巵偵憽傜傟傑偟偨丅暘巕婡夿偲偼丆僫僲儊乕僩儖僒僀僘偱恖岺揑偵惂屼偱偒傞婡夿偺偙偲偱偡偑丆偙偺3柤偺僲乕儀儖徿庴徿幰偼丆悽奅偵愭嬱偗偰暘巕儅僔儞偺晹昳乮暘巕僔儍僩儖丆暘巕儌乕僞乕丆暘巕僇乕乯傪嶌傝忋偘傑偟偨丅変乆偺恎偺夞傝偵偁傞婡夿偼丆偨偔偝傫偺晹昳偑揹巕夞楬偱屳偄偵楢寢偝傟婯懃惓偟偔摦嶌偡傞傛偆偵愝寁偝傟偰偄傑偡丅偦偆峫偊傞偲暘巕婡夿偵傕丆晹昳傪宷偖暘巕僒僀僘偺揹婥夞楬乮暘巕僨僶僀僗乯偑昁梫偵側傝傑偡乮恾侾乯[1]丅
恾侾.丂尰幚偺婡夿傗揹巕夞楬傪彫偝偔偟偰僫僲僗働乕儖偺暘巕婡夿傗暘巕夞楬丒暘巕慺巕傪
偮偔傠偆偲偄偆傾僀僨傾傪帵偟偰偄傑偡丅
丂暘巕僨僶僀僗偺峫偊曽偼丆惛枾偵僨僓僀儞偡傞偙偲偑壜擻側暘巕壔妛偺庤朄偱條乆側晹昳傪崌惉偟丄偝傜偵偦傟傜傪偮側偓崌傢偣偰堦偮偺戝偒側暘巕偵慻傒忋偘丄嫄戝側暘巕夞楬傗暘巕慺巕傪嶌傠偆偲偄偆傕偺偱偡丅1 nm乮僫僲儊乕僩儖乯偼1/109 m偲偄偆戝曄彫偝側悽奅傪堄枴偟傑偡偑丄偙偺傛偆側庤朄偱慻傒忋偘偨僫僲暘巕偼壔妛幰偐傜尒傟偽旕忢偵戝偒側悜鍟獛q苽葌鑲軅穪B偙偺傛偆側嫄戝暘巕傪惗傒弌偡偵偼丄嬥懏傗柍婡暔丄桳婡暔側偳條乆側尦慺傪巚偄偺傑傑偵慻傒忋偘偰偄偔崌惉媄弍偑昁梫偱偡偑丄摿偵嬥懏尨巕傪偮側偖偺偼戝曄擄偟偔婜懸偝傟傞傢傝偵偼悽奅揑偵傕側偐側偐恑揥偟偰偄傑偣傫丅巹偨偪偼丄嬥懏僀僆儞傗嬥懏尨巕偑桳婡暔偵傛偭偰庢傝姫偐傟偨偄傢備傞鄳畭鰬蹋偲偄偆暔幙傪埖偭偰偄傑偡偑丄嵟嬤偼僫僲僒僀僄儞僗偲偺娭楢偐傜丄懡悢偺嬥懏偑條乆側峔憿偱偮側偑傝偁偭偨嫄戝側暘巕乽嬥懏僋儔僗僞乕乿偺崌惉偲偦偺惈幙偵嫽枴傪帩偭偰偄傑偡丅摿偵丄揹巕偑朙晉偱巁壔忬懺偑掅偄嬥懏尨巕傪傑偭偡偖偮側偄偱暘巕偵偡傟偽丄暘巕僄儗僋僩儘僯僋僗偺婎杮偲傕偄偊傞乽嬥懏暘巕儚僀儎乕乮暘巕惈嬥懏嵔乯乿偲側傝傑偡丅巹偨偪偺尋媶幒偱偼丆嬥懏傪楢寢偡傞偺偵桳岠側懡嵗儂僗僼傿儞(懡悢偺儕儞傪娷傓壔崌暔)傪奐敪偟偰偒傑偟偨偑[2]丄偮偄嵟嬤丄偙偺愙拝嵻偺傛偆側壔崌暔傪梡偄傞偙偲偱丄婱嬥懏偺僷儔僕僂儉尨巕偑8屄傑偭偡偖偵寢崌偟椉抂偑桳婡壔崌暔偱僉儍僢僾偝傟偨嬥懏暘巕儚僀儎乕偺崌惉偵惉岟偟丄偦偺峔憿乮恾俀嵍乯傪嵟怴偺嫮椡X慄夞愜憰抲乮恾俀塃乯偱柧傜偐偵偟傑偟偨[3]丅偙傟偼丄拞惈偺嬥懏尨巕傪娷傓捈慄忬偺暘巕偲偟偰偼悽奅嵟挿乮栺3.5nm (35侌)乯偺暘巕儚僀儎乕偱偡乮摉帪偼嵟挿偱偟偨偑丆捈屻偵僷儔僕僂儉尨巕偑10屄偮側偑偭偨嬥懏儚僀儎乕偑崌惉偝傟偰偄傑偡[4]乯丅
恾俀丂巹偨偪偑崌惉偟偨僷儔僕僂儉尨巕偑8屄偮側偑偭偨嬥懏儚僀儎乕乮嵍乯偲丆
偦偺峔憿傪柧傜偐偵偟偨旝彫扨寢徎X慄夞愜憰抲乮塃乯丅
丂巹偨偪偑崌惉偟偨嬥懏暘巕儚僀儎乕偼丆4屄偺僷儔僕僂儉尨巕偑懡嵗儂僗僼傿儞乮棯崋dpmppm乯偱巟帩偝傟偨Pd4妀嵔偑俀偮楢寢偟偰Pd8妀嵔偲側偭偰偄傞偲偄偆懠偵偼側偄摿挜偑偁傝傑偡丅嬥懏儚僀儎乕偺椉枛抂偼丆桳婡暔偱僉儍僢僾偝傟偰偄傑偡偑丆偙偺僉儍僢僾傪偼偢偡偙偲傕壜擻偱偡丅傑偨丄壏搙偵傛偭偰怓偑曄壔偟嬥懏尨巕娫偺憡屳嶌梡偑曄壔偡傞偲偄偆戝曄嫽枴怺偄尰徾傪尒弌偟傑偟偨[3]丅偙傟偼丄岝傗壏搙偵傛偭偰嬥懏儚僀儎乕偺惈幙偑僗僀僢僠偡傞壜擻惈傪帵偟偰偄傑偡丅
恾俁丏Pd俉妀嬥懏暘巕儚僀儎乕偼100 oC埲忋偵壛擬偡傞偲俀偮偺Pd係妀儐僯僢僩偵暘棧偡傞偑丆
幒壏偵栠偡偲屳偄偵晄惸幆暿偟帺屓慻怐壔偡傞偙偲偱傕偲偺Pd俉妀嵔傪嵞惗偡傞丅
丂偝傜偵丆偙偺傛偆側嬥懏儚僀儎乕偼梟塼拞偱埨掕偱偡偑丆100亷埲忋偵壛擬偡傞偲俀偮偺Pd4妀儐僯僢僩偵暘棧偟丆嵞傃幒壏偵栠偡偲帺摦揑偵傕偲偺Pd8妀嵔偵栠傞偙偲偑妀帴婥嫟柭暘岝朄乮NMR乯偲偄偆暘愅庤抜偱暘偐傝傑偟偨丅峔憿扨埵偑帺慠偵偁傞摿挜揑側峔憿偑慻傒偁偑傞偙偲傪乽帺屓慻怐壔乮Self-Assembly乯乿偲偄偄傑偡偑丆嬥懏儚僀儎乕偑梟塼拞偱帺屓慻怐壔偡傞偙偲偼偙傟傑偱偵側偐偭偨尰徾偱偡[3], [5]丅傕偆偡偙偟徻偟偔尒偰偄偔偲丆嬥懏嵔偺巟帩偵梡偄偨懡嵗儂僗僼傿儞乮dpmppm乯偵偼塃庤偲嵍庤偺娭學偲側傞峔憿偑偱偒傞偲偙傠乮偙傟傪晄惸拞怱偁傞偄偼僉儔儖拞怱偲偄偆乯偑2偐強偁傞偨傔丆塃塃乮RR乯丆嵍嵍乮SS乯丆塃嵍乮RS乯偺棫懱堎惈懱偑懚嵼偟傑偡丅偦偺寢壥丆Pd4妀儐僯僢僩偵傕塃塃乮RR乯丆嵍嵍乮SS乯丆塃嵍乮RS乯偺棫懱堎惈懱偑偁傝傑偡偑乮恾俁忋乯丆帺屓慻怐壔偺夁掱偱屳偄偵帺暘偺僷乕僩僫乕傪尒偮偗偰傕偲偺Pd俉妀嬥懏儚僀儎乕傪惗惉偟傑偡乮恾俁壓乯[5]丅偙偺傛偆側尰徾偼丆晄惸幆暿傪捠偟偰摨偠庬椶偺晄惸棫懱峔憿偑廤愊偡傞僉儔儖僜乕僥傿儞僌乮Chiral Sorting乯偲傛偽傟傞戝曄捒偟偄帺屓慻怐壔偵嬫暿偝傟傑偡丅偪側傒偵丆巹偨偪惗偒暔偑傕偮僞儞僷僋幙傗DNA側偳傕僉儔儖僜乕僥傿儞僌偺偨傑傕偺偲偄偊傞偱偟傚偆丅尰嵼丆偙偺傛偆側僉儔儖僜乕僥傿儞僌傪奼挘偡傞偙偲偱偝傜偵挿偄嬥懏暘巕儚僀儎乕偺崌惉傗丆Pd4妀儐僯僢僩傪僠儏乕僯儞僌偡傞栚揑偱僷儔僕僂儉偲敀嬥傪娷傫偩崌嬥4妀嵔偺崌惉[6]偵庢傝慻傫偱偄傑偡丅
偝傜偵徻偟偄偙偲傪抦傝偨偄恖偺偨傔偵
[1] 拞搰棽峴丆扞悾抦柧丆壔妛 2017, 72, 66-67.
[2] Y. Takemura, H. Takenaka, T. Nakajima, T. Tanase, Angew. Chem. Int. Ed. 2009, 48, 2157-2161.
[3] K. Nakamae, Y. Takemura, B. Kure, T. Nakajima, Y. Kitagawa, T. Tanase, Angew. Chem. Int. Ed. 2015, 54, 1016-1021.
[4] S. Horiuchi, Y. Tachibana, M. Yamashita, K. Yamamoto, K. Masai, K. Takase, T. Matsutani, S. Kawamata, Y. Kurashige, T. Yanai, T. Murahashi, Nat. Commun. 2015, 6, 6742-6750.
[5] T. Tanase, K. Morita, R. Otaki, K. Yamamoto, Y. Kaneko, K. Nakamae, B. Kure, T. Nakajima, Chem. Eur. J. 2017, 23, 524-528.
[6] T. Tanase, M. Tanaka, M. Hamada, Y. Morita, K. Nakamae, Y. Ura, T. Nakajima, Chem. Eur. J. 2019, 25, 8219-8224.
尋媶幒偺儂乕儉儁乕僕: http://www.chem.nara-wu.ac.jp/~tanase/TanaseGroup/
