嵟怴偺尋媶徯夘

[ 儕儕乕僗丗 2016.02 ]
撧椙彈巕戝妛尋媶堾帺慠壢妛宯丂弝嫵庼丂屗揷姴恖

丂斀墳宱楬偼摶摴傪偨偳傞丅変乆偼嵟嬤丄婛偵妋棫偟偨偲巚傢傟偰偄偨偙偺愢偵曄峏傪敆傞丄怴偨側尰徾偺懚嵼傪梊應偟偨丅偙偙偱偼丄偙偺惉壥傊偲帄傞尋媶偺棳傟偲丄崱屻偺揥奐傪徯夘偡傞丅

斀墳宱楬傪挷傋傞

丂帺慠尰徾偵偼丄壔妛斀墳傗妀斀墳側偳丄斀墳偲屇偽傟傞尰徾偑怓乆偁傞丅偨偲偊偽巁慺偲悈慺傪崿偤崌傢偣丄揰壩偡傞偙偲偵傛偭偰悈傪惗惉偡傞壔妛斀墳偼偦偺堦椺偱偁傞丅偙偺傛偆側斀墳夁掱偼丄偳偺傛偆側宱楬傪偨偳偭偰恑峴偡傞偺偐丅斀墳夁掱偺偨偳傞宱楬偑暘偐傟偽丄偦偺斀墳偺恑峴傪懀恑偟偨傝丄媡偵抶傜偣偨傝側偳丄斀墳夁掱偺惂屼偡傜壜擻偵側傠偆丅偦偺傛偆側栤戣堄幆偵婎偯偄偰丄斀墳偺偨偳傞宱楬傪挷傋傛偆偲偡傞尋媶偑峴傢傟偰偒偨丅
丂偦偺嵺偵巜摫尨棟偲偟偰採弌偝傟偨偺偼丄乽斀墳宱楬偼摶摴傪偨偳傞乿偲偄偆愢偱偁傞丅傑偢摶摴偲偄偆傕偺傪愢柧偟偰偍偙偆丅尰嵼偺庒偄恖偨偪偵偼丄摶摴偺廳梫惈偑僺儞偲棃側偄壜擻惈偑偁傞偐傜偱偁傞丅摶偲偼丄慜曽偵偦傃偊傞嶳暲傒偵偍偄偰丄嵟傕掅偄埵抲偱岦偙偆懁偵墇偊傜傟傞抧揰偱偁傞丅幵傗揝摴偵傛傞堏摦偑慜採偲側偭偰偄傞崱擔丄栚偺慜偵嶳偑偁傟偽僩儞僱儖傪孈傞偺偑摉偨傝慜偲側偭偰偄傞丅偟偐偟丄偐偮偰恖乆偑曕偄偰嶳傪墇偊丄偦偺岦偙偆懁偵堏摦偡傞偲偒丄摶傪墇偊偰偄偔摴傪偨偳傞偙偲偑丄嵟彫偺楯椡乮埵抲僄僱儖僊乕乯偱丄嶳偺岦偙偆懁偵峴偗傞曽朄偩偭偨丅偨偲偊偽撧椙偐傜戝嶃偵帄傞摴偵偼丄埫乮偔傜偑傝乯摶側偳偄偔偮傕偺摶摴偑偁傞丅摨條偺峫偊偵婎偯偄偰丄乽斀墳宱楬偼摶摴傪偨偳傞乿偲偄偆愢偑崱擔丄巟攝揑偱偁傞丅偙偺愢偼偝傜偵恑傫偱丄斀墳偑惗偠傞抧宍乮億僥儞僔儍儖柺乯偺條巕傪夝愅偡傞偙偲偱丄斀墳宱楬傪棟夝偱偒傞偲偄偆愢傊偲敪揥偡傞丅偙傟偑丄暉堜尓堦乮僼儘儞僥傿傾揹巕棟榑偱僲乕儀儖壔妛徿傪庴徿乯傜偵傛偭偰採彞偝傟偨乽屌桳斀墳嵗昗( Intrinsic Reaction Coordinate棯偟偰IRC)乿偲偄偆棟榑偱偁傞丅
丂偟偐偟偙偺愢偱偼丄斀墳偑恑傫偱偄偔嵺偺懍搙偺岠壥偑柍帇偝傟偰偄傞丅恖娫偑曕偄偰嶳傪墇偊偰偄偔応崌傗丄搊嶳壠偑搊嶳儖乕僩傪専摙偡傞嵺偵偼丄抧宍偺夝愅偺傒偱椙偄偩傠偆丅偟偐偟搤婫僆儕儞僺僢僋嫞媄偺堦偮偱偁傞儃僽僗儗乕偱偼丄烉偑偨偳傞宱楬傪峫偊傞偵偼丄抧宍偵壛偊偰烉偺懍搙偑昁梫偱偁傞丅摨條偵壔妛斀墳偱傕丄懍搙偺塭嬁偑柍帇偟摼側偄応崌偑偁傞丅偦偺傛偆側尰徾偺堦偮偑丄嵟嬤丄変乆偑棟榑揑偵梊應偟偨乽斀墳宱楬偺愗傝懼偊乿偱偁傞丅

斀墳宱楬偺愗傝懼偊

丂偙偺傛偆側怴婯側尰徾傪梊應偡傞偵偼丄側傞傋偔扨弮側宯傪懳徾偵偡傞曽偑椙偄丅棟榑揑夝愅傪媈媊側偔峴側偆偙偲偑偱偒傞偟丄彨棃丄峴側傢傟傞偱偁傠偆幚尡揑専徹偵嵺偟偰傕丄崲擄偑傛傝彮側偄偲梊憐偝傟傞偐傜偱偁傞丅偦偺傛偆側娤揰偐傜変乆偑懳徾偲偟偨偺偼丄悈慺尨巕偺僀僆儞壔偱偁傞丅悈慺尨巕偵懳偟偰丄屳偄偵悅捈側曽岦傪岦偔惷揹応偲惷帴応傪壛偊丄儗乕僓乕偵傛偭偰崅椼婲忬懺偵椼婲偝傟偨揹巕偑丄僀僆儞壔偡傞嵺偺曽岦暘晍傪挷傋傞丅悈慺尨巕偵惷揹応傪壛偊傞偲丄揹巕偺僀僆儞壔偵僄僱儖僊乕忈暻偑惗偠傞偨傔丄僀僆儞壔偵嵺偟偰偺斀墳宱楬偼丄廬棃偺愢偵偟偨偑偊偽摶摴傪偨偳傞丅偙傟偵懳偟偰惷帴応偼丄懍搙偵斾椺偟偨椡傪揹巕偵壛偊丄揹巕偺塣摦偺岦偒傪曄偊傞岠壥傪惗傓丅摿偵丄惷帴応傪嫮偔偟偨傝丄揹巕偺懍搙傪戝偒偔偡傞偲丄偙偺岠壥偼嫮偔尰傟丄偮偄偵偼斀墳宱楬傪丄摶摴偲捈岎偡傞曽岦傊偲愗傝懼偊傞偵帄傞丅
丂偙偺條巕傪柾幃揑偵昤偄偨偺偑恾侾偱偁傞丅恾侾偱嵍壓偵昤偐傟偰偄傞偺偑悈慺尨巕乮梲巕偲揹巕偺懳乯偱偁傞丅廬棃偺愢偵傛傟偽丄揹巕偺僀僆儞壔偼摶摴傪偨偳傞丅偙偺摴偼丄嵍壓偐傜怢傃傞慄楬偱昞傢偝傟丄摶傪墇偊偰嶳偺岦偙偆懁傊崀傝偰偄偔丅偙偺摶摴偵捈岎偟偰昤偐傟偰偄傞偺偑丄愗傝懼偊屻偺斀墳宱楬偱偁傞丅斀墳宱楬偺僗僀僢僠偺懚嵼偑丄堎側傞慄楬傪愗傝懼偊傞僞乕儞僥乕僽儖偱昤偐傟偰偄傞丅偨偩偟恾1偵偼丄岆夝傪彽偔揰傕偁傞丅幚偼変乆偑梊應偟偨怴偟偄尰徾偼丄俀師尦偺抧宍忋傪堏摦偡傞斀墳偱偼婲偙傜側偄尰徾偱偁偭偰丄抧宍偑俁師尦埲忋偺斀墳偱偺傒惗偠傞丅墇偊傞傋偒嶳偺崅偝傕娷傔偰恾偵昤偔偨傔偵偼丄係師尦埲忋偑昁梫偲側傞丅偦偺傛偆側恾傪昤偔偙偲偼偱偒側偄偺偱丄偙偙偱偼惓妋偝傪媇惖偵偟偰昞尰偟偰偄傞丅偱偼丄 変乆偑梊應偟偨怴偨側尰徾偵偼丄側偤俁師尦埲忋偺抧宍偑昁梫側偺偐丅偦傟傪棟夝偡傞尞偑僇僆僗偱偁傞丅

恾1丗斀墳宱楬偺愗傝懼偊僗僀僢僠

僇僆僗偲偼壗偐

丂斀墳夁掱傪峫偊傞尋媶偱丄僇僆僗偑廳梫偲側傞丅偙偺揰偵丄変乆偺尋媶偺妛嵺揑側摿挜偑揟宆揑偵尰傟偰偄傞丅僇僆僗偲偼丄19悽婭枛偵僼儔儞僗偺悢妛幰億傾儞僇儗偑丄懢梲宯偵娭偡傞棟榑尋媶偺拞偱尒弌偟偨尰徾偱丄儔儞僟儉偵尒偊傞嬌傔偰暋嶨側塣摦偑丄斾妑揑娙扨側曽掱幃偐傜偝偊惗偠傞偙偲傪尵偆丅偦偺屻丄僇僆僗偼婥徾丒惗懱丒宱嵪側偳條乆側尰徾偱敪尒偝傟丄帺慠偲幮夛偵搉傞晛曊揑尰徾偱偁傞偙偲偑暘偐偭偰偄傞丅斀墳宱楬傪峫偊傞応崌傕丄僇僆僗傪峫偊傞偙偲偑杮幙揑偱偁傞丅恾1偱偼丄俀師尦偺抧宍偺拞傪堏摦偡傞応崌丄摶摴偵捈岎偡傞曽岦偼1師尦偱偁傞丅偙傟偵懳偟偰俁師尦偺抧宍傪堏摦偡傞応崌丄摶摴偵捈岎偡傞曽岦偼俀師尦偲側傝丄偦偙偵僇僆僗偑敪惗偡傞壜擻惈偑偁傞丅偙偺僇僆僗偺懚嵼偑乽斀墳宱楬偺愗傝懼偊乿傪堷偒婲偙偡偺偱偁傞丅

崱屻偺揥奐

丂変乆偑梊應偟偨怴偨側尰徾偼丄儗乕僓乕偵傛傞旕暯峵斀墳夁掱傗丄塅拡偵偍偗傞壔妛斀墳偱廳梫偲側傠偆丅嬤擭丄惗柦偺尦偲側傝摼傞傾儈僲巁偑塅拡偵懚嵼偡傞壜擻惈偑帵偝傟丄塅拡偵偍偗傞壔妛斀墳偺尋媶偑丄塅拡壔妛偲屇偽傟娭怱傪屇傫偱偄傞丅偙偺傛偆側墳梡偱壽戣側偺偼丄検巕椡妛偵偍偗傞斀墳宱楬偺僗僀僢僠偱偁傞丅尰帪揰偱偺変乆偺尋媶偼屆揟僇僆僗偵婎偯偔偑丄嬤擭丄検巕僇僆僗偺尋媶偑恑揥偟丄僩儞僱儖岠壥傪娷傔偰怴偨側検巕尰徾偺壜擻惈偑巜揈偝傟偰偄傞丅斀墳宱楬偺愗傝懼偊偵娭偟偰傕怴婯側検巕尰徾偺壜擻惈偑偁傝丄崱屻偺尋媶偺揥奐偑婜懸偱偒傞丅

幱帿

杮尋媶偼丄杒奀摴戝妛揹巕壢妛尋媶強偺帥杮墰彆嫵丒彫徏嶈柉庽嫵庼丄搶杒戝妛懡尦暔幙壢妛尋媶強偺崅嫶惓旻嫵庼丄搶杒戝妛戝妛堾棟妛尋媶壢偺壨栰桾旻嫵庼偲偺嫟摨尋媶偱偁傝丄杒奀摴戝妛丒搶杒戝妛丒搶嫗岺嬈戝妛丒戝嶃戝妛丒嬨廈戝妛偺5晬抲尋媶強偺僱僢僩儚乕僋宆偵傛傞暥晹壢妛徣乽暔幙丒僨僶僀僗椞堟嫟摨尋媶嫆揰乿丄偍傛傃擔杮妛弍怳嫽夛傛傝壢尋旓婎斦尋媶C丒挧愴揑朑夎尋媶偺巟墖傪庴偗偨丅杮尋媶惉壥偼丄暔棟妛偺暘栰偱嵟崅曯偺儗僞乕帍偱偁傞Physical Review Letters偵宖嵹偝傟丄偦偺嵺偵Editor傛傝僾儗僗儕儕乕僗傪峴側偆傛偆姪傔傜傟偨丅偙傟傪庴偗偰杒奀摴戝妛丒搶杒戝妛偱僾儗僗儕儕乕僗傪峴偄丄擔宱嶻嬈怴暦摍偵宖嵹偝傟偰偄傞丅側偍恾1偼丄杒奀摴戝妛丒搶杒戝妛偵偍偗傞僾儗僗儕儕乕僗偵嵺偟偰梡偄偨傕偺偱偁傞丅

杮尋媶偵娭偡傞榑暥偼埲壓偺捠傝偱偁傞丅

(1)Mechanism and Experimental Observability of Global Switching Between Reactive and Nonreactive Coordinates at High Total Energies, Hiroshi Teramoto, Mikito Toda, Masahiko Takahashi, Hirohiko Kono, and Tamiki Komatsuzaki, Phys. Rev. Lett. 115, 093003, 2015
http://journals.aps.org/prl/abstract/10.1103/PhysRevLett.115.093003

(2)Breakdown mechanisms of normally hyperbolic invariant manifolds in terms of unstable periodic orbits and homoclinic/heteroclinic orbits in Hamiltonian systems,
Hiroshi Teramoto, Mikito Toda and Tamiki Komatsuzaki1,
Nonlinearity, Volume 28, Number 8丂pp.2677-2698, 2015
http://iopscience.iop.org/article/10.1088/0951-7715/28/8/2677/meta

(3)Dynamical Switching of a Reaction Coordinate to Carry the System through to a Different Product State at High Energies, Hiroshi Teramoto, Mikito Toda, and Tamiki Komatsuzaki, Phys. Rev. Lett. 106, 054101 2011,
http://journals.aps.org/prl/abstract/10.1103/PhysRevLett.106.054101