嵟怴偺尋媶徯夘

[ 儕儕乕僗丗 2015.12 ]
撧椙彈巕戝妛棟妛晹丂壔妛惗柦娐嫬妛壢丂壔妛僐乕僗丒娐嫬壢妛僐乕僗寭扴丂嶰曽桾巌

丂巹偨偪偑惗柦妶摦傪堐帩偡傞忋偱丄寚偐偣側偄懚嵼偱偁傞峺慺丅峺慺偵偼丄乽婎幙摿堎惈乿偲偄偆惈幙偑偁傝丄偦傟偧傟偺峺慺偼摿掕偺暔幙偵懳偟偰偺傒慖戰揑偵斀墳偟偰丄惗懱斀墳傪岠棪揑偵恑峴偝偣偰偄傞丄偲偄偆偙偲偼奆偝傫傕偛懚偠偱偼側偄偱偟傚偆偐丅偟偐偟丄峺慺偵尷傜偢丄巹偨偪偺懱傪嶌偭偰偄傞偝傑偞傑側暘巕偼丄懱撪偵娷傑傟傞暿偺暘巕傗嬥懏僀僆儞傪尩枾偵幆暿偟偰偄傑偡丅偙偺“幆暿”傪僼儔僗僐偺拞偱嵞尰偡傞偙偲偱丄傑偩傑偩撲偑懡偄“惗懱婡擻偺夝柧”偵敆傞偙偲偑偱偒傞偺偱偼側偄偐亅丅偦傫側栰朷傪嫻偵丄巹偺尋媶幒偱偼丄乽偝傑偞傑側嬥懏僀僆儞傪柧妋偵幆暿偱偒傞暘巕偺愝寁偍傛傃崌惉乿偵偮偄偰尋媶傪峴偭偰偄傑偡丅杮峞偱偼丄懡偔偺惗柦妶摦偵娭傢偭偰偍傝丄惗懱偵偲偭偰旕忢偵廳梫側嬥懏偱偁傞垷墧僀僆儞丄娐嫬拞偵懚嵼偡傞撆惈偺崅偄廳嬥懏偱偁傞僇僪儈僂儉僀僆儞丒悈嬧僀僆儞傪偦傟偧傟摿堎揑偵尒暘偗傞偙偲偑偱偒傞寀岝僙儞僒乕暘巕偺奐敪偵偮偄偰丄嵟嬤偺尋媶惉壥傪徯夘偟傑偡丅

丂傑偢丄垷墧僀僆儞傪摿堎揑偵尒暘偗傞僙儞僒乕偵偮偄偰徯夘偟傑偡丅巹偺尋媶幒偱偼丄乽僉僲儕儞乿偲偄偆壔崌暔偵拝栚偟丄怓乆側壔崌暔偺崌惉偵庢傝慻傫偱偒傑偟偨丅偼偠傔偵丄乽僄僠儗儞僕傾儈儞乿偵4偮偺乽僉僲儕儞乿傪寢崌偟偨TQEN偲偄偆壔崌暔偺崌惉傪峴偄傑偟偨乮恾1嵍乯丅TQEN偼垷墧僀僆儞傪曔傑偊傞乮乽嶖懱乿傪宍惉偡傞乯偲岝傞丄偲偄偆惈幙傪桳偡傞偙偲偑暘偐傝傑偟偨丅偟偐偟丄摨懓尦慺偱偁傞僇僪儈僂儉僀僆儞傪曔傑偊偨応崌偵傕垷墧僀僆儞傪曔傑偊偨偲偒偺60亾掱搙偺嫮搙偱岝偭偰偟傑偄丄垷墧偵懳偡傞摿堎惈傪傛傝崅傔傞昁梫偑偁傞偙偲偑暘偐傝傑偟偨丅TQEN偺垷墧嶖懱偺X慄寢徎峔憿夝愅傪峴偭偰峔憿傪妋擣偟偨偲偙傠丄暘巕撪偺僉僲儕儞娐摨巑偺棫懱忈奞偑戝偒偔側偭偰偄傞偙偲偑暘偐傝傑偟偨丅偦偺偨傔丄TQEN偼嶖懱偺峔憿偑垷墧僀僆儞偵懳偟偰偁傑傝偆傑偔僼傿僢僩偟偰偍傜偢丄垷墧僀僆儞偵懳偡傞摿堎惈偑寚偗偰偄傞偺偱偼側偄偐偲峫偊傑偟偨丅偦偙偱丄TQEN偺4偮偺乽僉僲儕儞乿傪乽僀僜僉僲儕儞乿偵抲偒姺偊偨1-isoTQEN偺崌惉傪峴偭偨偲偙傠丄垷墧嶖懱宍惉帪偺棫懱忈奞傪庢傝嫀傞偙偲偵惉岟偟丄垷墧僀僆儞偵懳偟偰偟偭偐傝偲僼傿僢僩偟偨丄垷墧僀僆儞摿堎揑寀岝僙儞僒乕暘巕偺奐敪偵惉岟偟傑偟偨乮恾1拞墰乯丅

恾侾丂TQEN乮嵍乯丆垷墧僀僆儞僙儞僒乕1-isoTQEN乮拞墰乯偍傛傃悈嬧僀僆儞僙儞僒乕BQET乮塃乯

丂傑偨丄TQEN偺乽僄僠儗儞乿晹埵傪乽僔僋儘僿僉僒儞乿偲偡傞偙偲偵傛傝崌惉偟偨壔崌暔TQDACH傕丄垷墧僀僆儞摿堎揑寀岝僙儞僒乕偲側傞偙偲傪尒弌偟傑偟偨乮恾2嵍乯丅偲偙傠偑丄TQDACH偺乽僔僋儘僿僉僒儞乿傪乽儀儞僛儞乿偲偟偨壔崌暔TQPHEN偼慡偔媡偺嫇摦傪帵偟丄僇僪儈僂儉僀僆儞摿堎揑寀岝僙儞僒乕偲側傞偙偲偑暘偐傝傑偟偨乮恾2塃乯丅壔崌暔偺峔憿傪傎傫偺彮偟曄偊傞偩偗偱丄尒暘偗傞偙偲偑偱偒傞嬥懏偑曄傢傞丄偲偄偆嫽枴怺偄寢壥偑傕偨傜偝傟傑偟偨丅

丂偝偰丄偙傟偱垷墧僀僆儞偲僇僪儈僂儉僀僆儞傪摿堎揑偵擣幆偡傞僙儞僒乕傪嶌傞偙偲偑偱偒傑偟偨丅懕偄偰悈嬧僀僆儞偵懳偡傞僙儞僒乕偵偮偄偰偱偡丅巹偨偪偼丄乽帡偨幰摨巑偼拠偑椙偄乿偲偄偆壔妛偺朄懃傪僸儞僩偵丄悈嬧僀僆儞僙儞僒乕偺愝寁傪峴偄傑偟偨丅嬶懱揑偵偼丄廃婜昞偺壓偺曽偵偁傞乽僜僼僩側尨巕乿偱偁傞悈嬧傪擣幆偡傞偨傔偵丄拏慺乮N乯傛傝傕乽僜僼僩側尨巕乿偱偁傞棸墿乮S乯傪娷傓BQET傪愝寁偟丄崌惉傪峴偄傑偟偨乮恾1塃乯丅堦斒揑偵丄悈嬧偺傛偆側廳嬥懏偼丄“徚岝”乮嬥懏傪曔傑偊偰傕岝傜側偄乯偲偄偆惈幙偑偁傞偨傔丄悈嬧傪曔傑偊偰岝傞僙儞僒乕偺奐敪偼戝曄嬯楯偟傑偟偨丅偟偐偟丄杮尋媶偱偼巹偨偪偺愴棯偑偆傑偔偄偒丄悈嬧傪曔傑偊偰岝傞僙儞僒乕丄BQET偺奐敪偵惉岟偟傑偟偨丅

丂埲忋偺傛偆偵丄嵟弶偵崌惉偟偨TQEN偺峔憿傪尦偲偟偰丄垷墧僀僆儞丒僇僪儈僂儉僀僆儞丒悈嬧僀僆儞偦傟偧傟偵懳偡傞僙儞僒乕壔崌暔傪奐敪偡傞偙偲偑偱偒傑偟偨丅壔崌暔偺峔憿傪彮偟曄偊傞偩偗偱丄偦偺婡擻偑寑揑偵曄壔偡傞偲偄偆偙偲偑偍暘偐傝捀偗偨偱偟傚偆偐丅“傗偭偰傒側偄偲暘偐傜側偄”偦傫側壔妛偺枺椡偵庢傝溸偐傟丄怴偟偄婡擻傪敪婗偡傞暘巕偺敪尒傪柌尒偰丄尋媶幒偺妛惗偨偪偼擔乆怴偟偄壔崌暔偺崌惉偵庢傝慻傫偱偄傑偡丅偁側偨傕巹偨偪偲堦弿偵丄悽奅偱弶傔偰偺暘巕傪嶌偭偰丄帺慠奅偺恄旈偵挧愴偟偰傒傑偣傫偐丅

恾俀丂垷墧僀僆儞僙儞僒乕TQDACH乮嵍乯偍傛傃僇僪儈僂儉僀僆儞僙儞僒乕TQPHEN乮塃乯

娭楢榑暥

(1) Y. Mikata, R. Ohnishi, A. Ugai, H. Konno, Y. Nakata, I. Hamagami, and S. Sato
OFF-ON-OFF fluorescent response of N,N,N乫,N乫-tetrakis(1-isoquinolylmethyl)-2-hydroxy-1,3-propanediamine (1-isoHTQHPN) toward Zn²⁺
Dalton Trans., 45(17), 7250-7257 (2016).
http://pubs.rsc.org/en/content/articlelanding/2016/dt/c6dt00506c

(2) Y. Mikata, A. Kizu and H. Konno
TQPHEN (N,N,N乫,N乫-tetrakis(2-quinolylmethyl)-1,2-phenylenediamine) derivatives as highly selective fluorescent probes for Cd²⁺
Dalton Trans., 44(1), 104-109 (2015).
http://pubs.rsc.org/en/content/articlelanding/2015/dt/c4dt02177k